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    Behavior Of Plants In Unventilated Chambers

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    Peer Reviewedhttps://deepblue.lib.umich.edu/bitstream/2027.42/142325/1/ajb205503.pd

    Observations from a prototype implementation of the Common APSE Interface Set (CAIS)

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    This paper presents an overview of the Common Ada Programming Support Environment (APSE) Interface Set (CAIS), its purpose, and its history. The paper describes an internal research and development effort at the Mitre Corporation to implement a prototype version of the current CAIS specification and to rehost existing Ada software development tools onto the CAIS prototype. Based on this effort, observations are made on the maturity and functionality of the CAIS. These observations support the government's current policy of publicizing the CAIS specification as a baseline for public review in support of its evolution into a standard which can be mandated for use as Ada is today

    Electronic structure, phase stability and chemical bonding in Th2_2Al and Th2_2AlH4_4

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    We present the results of theoretical investigation on the electronic structure, bonding nature and ground state properties of Th2_2Al and Th2_2AlH4_4 using generalized-gradient-corrected first-principles full-potential density-functional calculations. Th2_2AlH4_4 has been reported to violate the "2 \AA rule" of H-H separation in hydrides. From our total energy as well as force-minimization calculations, we found a shortest H-H separation of 1.95 {\AA} in accordance with recent high resolution powder neutron diffraction experiments. When the Th2_2Al matrix is hydrogenated, the volume expansion is highly anisotropic, which is quite opposite to other hydrides having the same crystal structure. The bonding nature of these materials are analyzed from the density of states, crystal-orbital Hamiltonian population and valence-charge-density analyses. Our calculation predicts different nature of bonding for the H atoms along aa and cc. The strongest bonding in Th2_2AlH4_4 is between Th and H along cc which form dumb-bell shaped H-Th-H subunits. Due to this strong covalent interaction there is very small amount of electrons present between H atoms along cc which makes repulsive interaction between the H atoms smaller and this is the precise reason why the 2 {\AA} rule is violated. The large difference in the interatomic distances between the interstitial region where one can accommodate H in the acac and abab planes along with the strong covalent interaction between Th and H are the main reasons for highly anisotropic volume expansion on hydrogenation of Th2_2Al.Comment: 14 pages, 9 figure
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